[RuCl(p-cymene)((R)-segphos(regR))]Cl - Names and Identifiers
Name | Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride
|
Synonyms | (R)RuCl[(pcyMene)(SEGPHOS)]Cl [RUCL(P-CYMENE)((R)-SEGPHOS)]CL [RuCl(p-cymene)((R)-segphos(regR))]Cl -bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((R)-segphos Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride CHLORO[(R)-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE](P-CYMENE)RUTHENIUM(II) CHLORIDE,[RUCL(P-CYMENE)((R)-SEGPHOS Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos(R))]Cl
|
CAS | 944451-28-9
|
[RuCl(p-cymene)((R)-segphos(regR))]Cl - Physico-chemical Properties
Molecular Formula | C48H40Cl2O4P2Ru
|
Molar Mass | 914.76 |
Melting Point | >100°C |
Water Solubility | Insoluble in water |
Appearance | Powder |
Color | yellow |
Storage Condition | 2-8°C |
Sensitive | air sensitive |
[RuCl(p-cymene)((R)-segphos(regR))]Cl - Risk and Safety
[RuCl(p-cymene)((R)-segphos(regR))]Cl - Introduction
Chloro[(R)-( )-5,5 '-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride is an organometallic compound containing a ruthenium metal center in its structure and the ligand is (R)-( )-5,5 '-bis (diphenylphosphine)-4,4'-bis-1, 3-benzodioxolane and p-toluene.
Nature:
-Appearance: White crystalline solid
-melting point: about 180-185 ℃
-Solubility: Good solubility in non-polar solvents
Use:
Chloro[(R)-( )-5,5 '-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride are widely used as catalysts in organic synthesis. It is usually used to catalyze asymmetric hydrogenation, asymmetric addition and asymmetric cyclization reactions, and can be used to synthesize organic compounds with chirality.
Preparation Method:
Preparation of Chloro[(R)-( )-5,5 '-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride is usually prepared by mixing (R)-( )-5,5 '-bis (diphenylphosphine)-4,4'-bis -1 in the presence of ruthenium chloride, 3-benzodioxolane and toluene reaction.
Safety Information:
Chloro[(R)-( )-5,5 '-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride is an organometallic compound and needs to be handled and handled in accordance with safety procedures. It may be harmful to the human body, contact or inhalation may cause irritation, difficulty breathing, eye and skin damage, etc. Use in well-ventilated conditions and wear appropriate protective equipment such as gloves, goggles and protective clothing. In the event of contact or accidental exposure, clean the affected area immediately and seek medical help.
Last Update:2024-04-09 15:18:01